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Tellurium tetrachloride 16 was widely used in the past to introduce tellurium into organic substrates. It reacts with several functional groups giving organotellurium trichlorides 5 (X = Cl), which constitute an important class of tellurium electrophiles. Tellurium tetrachloride 16 is prepared by passing a stream of dry chlorine over elemental tellurium in an appropriate glass apparatus ...

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